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Open Access Crystal structure of dichloridobis(N,N′-dimethylthiourea-κS)mercury(II)

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The molecular structure of the title compound, [HgCl2(C3H8N2S)2], has point group symmetry 2, with the twofold rotation axis passing through the HgII atom. The latter is coordinated by two Cl atoms and two N,N′-dimethylthiourea (Dmtu) ligands through their S atoms, defining a distorted tetrahedral coordination sphere with bond angles in the range 102.47 (4)–118.32 (4)°. Intra- and intermolecular hydrogen bonds of the type N—H...Cl with S(6) and R22(12) ring motifs are present. The intermolecular contacts make up polymeric chains extending parallel to [101].
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Document Type: Research Article

Affiliations: 1: Department of Chemistry, University of Sargodha, Sargodha, Punjab, Pakistan 2: Department of Chemistry, University of Engineering and Technology, Lahore 54890, Pakistan 3: Department of Physics, University of Sargodha, Sargodha, Punjab, Pakistan 4: Department of Chemistry, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi Arabia

Publication date: January 1, 2015

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