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Open Access Crystal structure of 6,6,12,12-tetrachlorotricyclo[8.2.0.04,7]dodecane-5,11-dione

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The asymmetric unit of the title compound, C12H12Cl4O2, contains two crystallographically independent molecules with almost identical conformations (r.m.s. overlay fit for the non-hydrogen atoms = 0.059 Å). In each molecule, the central eight-membered ring has a distorted boat configuration, and two non-planar four-membered rings are fused on either side of the eight-membered ring. A weak C—H...O hydrogen bond links the two independent molecules. In the crystal, weak C—H...O hydrogen bonds link the molecules into a two-dimensional network parallel to (001).
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Document Type: Research Article

Affiliations: 1: Department of Chemistry, Atatürk University, 25240, Erzurum, Turkey 2: Department of Physics, Hacettepe University, 06800 Beytepe, Ankara, Turkey

Publication date: January 1, 2015

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