Skip to main content
padlock icon - secure page this page is secure

Open Access Crystal structures of 1-(4-chlorophenyl)-2-(diphenylphosphoryl)ethan-1-one and 1-(diphenylphosphoryl)-3,3-dimethylbutan-2-one

Download Article:

The full text article is available externally.

The article you have requested is supplied via the DOAJ. View from original source.

The title compounds, C20H16ClO2P, (I), and C18H21O2P, (II), were synthesized via an Arbuzov reaction between an α-bromoketone and isopropoxydiphenylphosphane. In the crystals of both compounds, molecules are linked via bifurcated C—H...(O,O) hydrogen bonds, forming chains propagating along [100] for (I) and along [010] for (II). The chains are linked via C—H...π interactions, leading to the formation of sheets lying parallel to (010) for (I) and (001) for (II). The absolute structure of compound (II) was determined by resonant scattering [Flack parameter = 0.088 (14)].
No References
No Citations
No Supplementary Data
No Article Media
No Metrics

Document Type: Research Article

Affiliations: 1: Department of Chemistry, Grand Valley State University, 1 Campus Dr., Allendale, MI 49401, USA 2: Center for Crystallographic Research, Department of Chemistry, Michigan State University, 578 S. Shaw Lane, East Lansing, MI 48824, USA

Publication date: January 1, 2015

  • Access Key
  • Free content
  • Partial Free content
  • New content
  • Open access content
  • Partial Open access content
  • Subscribed content
  • Partial Subscribed content
  • Free trial content
Cookie Policy
X
Cookie Policy
Ingenta Connect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more