@article {Tarek:2015:2056-9890:498, title = "Crystal structure of a new hybrid antimonyhalide-based compound for possible non-linear optical applications", journal = "Acta Crystallographica Section E: Crystallographic Communications", parent_itemid = "infobike://doaj/20569890", publishercode ="doaj", year = "2015", volume = "71", number = "5", publication date ="2015-01-01T00:00:00", pages = "498-501", itemtype = "ARTICLE", issn = "2056-9890", url = "https://www.ingentaconnect.com/content/doaj/20569890/2015/00000071/00000005/art00017", doi = "doi:10.1107/S2056989015007379", author = "Tarek Ben Rhaiem and Habib Boughzala", abstract = "The hybrid title compound, catena-poly[[[bis(1,4-diazoniabicyclo[2.2.2]octane) [tetraachloridoantimonate(III)]--chlorido-[tetrachloridoantimonate(III)]--chlorido]] monohydrate], {(C6H14N2)2[Sb2Cl10]H2O}n, is self-assembled into alternating organic and inorganic layers parallel to the bc plane. The anionic inorganic layer consists of infinite zigzag chains of corner-sharing [SbCl6]3 octahedra running along the b axis. The organic part is made up of 1,4-diazoniabicyclo[2.2.2]octane dications (dabcoH22+). The water molecules in the structure connect inorganic and organic layers. Hydrogen-bonding interactions between the ammonium groups, water molecules and Cl atoms ensure the structure cohesion.", }