Skip to main content
padlock icon - secure page this page is secure

Crystal Structure and Nuclear Density Distribution of LiCo1/3Ni1/3Mn1/3O2 Analyzed by Rietveld/Maximum Entropy Method

Buy Article:

$52.00 + tax (Refund Policy)

The neutron powder diffraction measurement of LiCo1/3Ni1/3Mn1/3O2 was carried out and the crystal structure and scattering density distribution were analyzed by Rietveld refinement and the maximum entropy method (MEM) to estimate the Li diffusing pathway. Rietveld refinement showed that the structure was basically the same as LiCoO2: a R-3m space group, with Li and O mainly occupying the 3a and 6c sites, and Co, Ni, and Mn randomly occupying the 3b site. Approximately 4% of the Li and Ni atoms exchanged their original sites (3a and 3b) to occupy 3b and 3a, respectively. Based on MEM analyses, we surmise that Li atoms moved on the (001), (003), and (00-3) planes and diffused through the 3a–9e–3a sites on these planes.
No References
No Citations
No Supplementary Data
No Article Media
No Metrics

Document Type: Research Article

Affiliations: Quantum Beam Science Directorate, Japan Atomic Energy Agency, Tokai-mura, Ibaraki-ken 319-1195, Japan

Publication date: August 1, 2010

  • Access Key
  • Free content
  • Partial Free content
  • New content
  • Open access content
  • Partial Open access content
  • Subscribed content
  • Partial Subscribed content
  • Free trial content
Cookie Policy
Cookie Policy
Ingenta Connect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more