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Electrochemical Synthesis of Barium Tungstate Crystallites with Different Morphologies: Effect of Electrolyte Components

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Barium tungstate crystallites with different sizes and morphologies were successfully synthesized using a simple electrochemical technique by varying the components of electrolyte solutions. XRD analysis evidenced that the as-prepared samples were a pure tetragonal-phase of BaWO4 with a scheelite structure. Scanning electron microscopy images and PL spectra of BaWO4 crystallites revealed that the presence of OH ions and the incorporation of absolute ethanol into the electrolyte solution would have important effects on their particle sizes, morphologies, and optical properties.
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Document Type: Research Article

Affiliations: 1: State Key Laboratory of Green Building Materials, China Building Materials Academy, Beijing 100024, China 2: Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266003, China

Publication date: October 1, 2009

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