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Synthesis of Micron-Scale Platelet BaTiO3

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Micron-scale platelet barium titanate was synthesized using a twostep molten salt and topochemical technique. Plate-like BaBi4Ti4O15 was first synthesized as a precursor by molten salt synthesis. Then, Bi3+ in the precursor was replaced by Ba2+ and formed perovskite-structure BaTiO3 through a topochemical reaction. The BaTiO3 single crystals have an average size of 5–10 m and a thickness of 0.5 m. The purpose of this article is to control the particle shape with desired structure. High aspect ratio BaTiO3 platelets are suitable templates to obtain textured ceramics (especially Pb(Mg1/3Nb2/3)O3–32.5PbTiO3) by the templated grain growth process.
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Document Type: Research Article

Affiliations: State Key Laboratory of New Ceramics and Fine Processing, Department of Materials Science and Engineering, Tsinghua University, Beijing 100084, China

Publication date: April 1, 2007

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