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Preparation of Single-Phase High Tc Superconductor (Bi,Pb)2Sr2Ca2Cu3Ox (2223) with Hg Substitution

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The successful preparation of single-phase Hg-doped (2223) using a nitrate decomposition/solid state reaction method is described in this paper. The effects of Hg doping on the formation of single-phase (2223) have been investigated by X-ray and synchrotron radiation diffraction. When compared with Pb-doped system, the use of Hg as a dopant has resulted in the reduction of both the final sintering temperature and the annealing time of the single-pure (2223) material, without any obvious deterioration of the superconducting properties.
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Document Type: Research Article

Affiliations: Materials Research Group, Department of Applied Physics, Curtin University of Technology, Perth, WA 6845, Australia

Publication date: May 1, 2005

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