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The polyfunctionalized en­amino­ne ethyl [(Z)-2-(2,2-di­methyl-4,6-dioxo-1,3-dioxan-5-yl­idene­methyl)-1-methyl-3-oxo-but-1-enyl­amino]­acetate

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The solid-state structure of the title en­amino­ne, C15H17N1O7, the C adduct obtained from the reaction of 4-amino­pent-3-en-2-one with methoxy­methyl­ene Meldrum's acid, has been investigated by X-ray diffraction, and several structural features are different from the previously described structure of the corresponding N adduct. The carbonyl group of the en­amino­ne moiety of the C adduct is not coplanar with the en­amine fragment. One bifurcated intramolecular N—H…O hydrogen bond [2.688 (2) and 2.668 (2) Å] and two intermolecular C—H…O hydrogen bonds [3.339 (3) and 3.379 (3) Å] are observed. The structure packs in a linear fashion along the [100] direction.
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Document Type: Research Article

Publication date: December 1, 2004

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