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Benzyl­idene­acetone 2,4-di­nitro­phenyl­hydrazone

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Crystals of the title compound, C16H14N4O4, were obtained from a condensation reaction of benzyl­idene­acetone and 2,4-di­nitro­phenyl­hydrazine. The mol­ecule has a nearly planar structure with a dihedral angle of 7.57 (4)° between the di­nitro­phenyl and benzyl­idene mean planes. Within the di­nitro­phenyl moiety, the distances of 1.420 (2) and 1.411 (3) Å for the C—C bonds near the imine group are longer than the average distance of 1.374 (3) Å for the other C—C bonds in the same benzene ring. The short N—C distance of 1.338 (2) Å indicates electron delocalization between the imine group and di­nitro­phenyl ring.
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Document Type: Research Article

Publication date: December 1, 2004

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