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Bis(2-pyrimidinyl) di­sulfide dihydrate: a redetermination

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The crystal structure of bis(2-pyrimidinyl) di­sulfide dihydrate, C8H6N4S2·2H2O, has been redetermined using CCD diffractometer data. This has allowed for a more precise location of the water H atoms and shows the water mol­ecules forming unusual spiral hydrogen-bonded aqua columns, as well as giving inter-column crosslinks through the pyrimidine N-atom acceptors of the di­sulfide mol­ecules. The structural chemistry of aromatic di­sulfides has also been reviewed.
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Document Type: Research Article

Publication date: December 1, 2004

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