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p-Tolyl 2,3-an­hydro-5,6-O-iso­propyl­idene-1-thio--d-gulo­furan­oside

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In the title compound, C16H20O4S, the epoxide ring is trans to the p-tolyl group and cis to the dioxolane moiety. The furan­ose ring adopts a conformation in which the furan­ose and epoxide O atoms are on the same face of the mol­ecule (EO) and the p-tolyl group adopts the conformation favored by the exo-anomeric effect, gauche to the ring O atom and anti to the ring C atom.
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Document Type: Research Article

Publication date: December 1, 2004

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