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catena-Poly­[[-ethyl­enedi­amine-2N:N′-bis­[(ethyl­enedi­amine-2N,N′)silver(I)] bis[silver(I)--barbiturato-2N:N′]] dihydrate]

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The title compound, {[Ag2(C2H8N2)3][Ag2(C8H10N2O3)2]·2H2O}n, consists of one-dimensional polymeric silver(I) complex anionic chains, discrete dinuclear silver(I) complex cations and solvent water mol­ecules. In the anionic chain, each AgI atom is coordinated by two deprotonated N atoms from two barbiturate ligands in a perfectly linear geometry. In the dinuclear silver(I) complex cation, each AgI atom, in a Y-shaped coordination environment, is coordinated by three N atoms from two ethyl­enedi­amine mol­ecules. The bridging ethylenediamine ligand and the Ag atoms of the anionic chain lie on inversion centres.
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Document Type: Research Article

Publication date: December 1, 2004

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