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(-Bi­phenyl-4,4′-di­carboxyl­ato)­bis­[(2-amino­pyridine)silver(I)]

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The title compound, [Ag2(C14H8O4)(C5H6N2)2], is a dinuclear AgI complex which has crystallographic inversion symmetry. Each Ag atom is three-coordinated by two N atoms from two 2-amino­pyridine ligands and by one O atom from a bi­phenyl-4,4′-di­carboxyl­ate ligand, giving a Y-shaped coordination environment. Two AgI atoms are linked through a bi­phenyl-4,4′-di­carboxyl­ate ligand, acting as a bridge, forming a dimeric complex. The separation between the two silver(I) centres is 15.879 (3) Å. In the crystal structure, mol­ecules are connected by N—H…O hydrogen bonds, forming molecular tapes in the a-axis direction.
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Document Type: Research Article

Publication date: December 1, 2004

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