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Bis(-4-chloro­benzoato-2O:O′)­bis­[(2-amino­pyridine-N)silver(I)](Ag—Ag) monohydrate

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The title complex, [Ag2(C7H4ClO2)2(C5H6N2)2]·H2O, lies about an inversion center, with the water molecule on a twofold rotation axis, and the AgI atom is three-coordinated by two O atoms from two different but symmetry-related 4-chloro­benzoate anions and one N atom from one 2-amino­pyridine ligand. The 4-chloro­benzoate anion acts as a bidentate ligand, bridging two inversion-related Ag atoms of the complex and forming a dimer. In the crystal structure, the mol­ecules are linked through intramolecular and intermolecular N—H…O and O—H…O hydrogen bonds, forming two-dimensional layers parallel to the bc plane.
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Document Type: Research Article

Publication date: December 1, 2004

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