Poly[triaqua(-benzene-1,3-dioxyacetato)manganese(II)]: a two-dimensional manganese(II) coordination polymer
In the asymmetric unit of the title compound, [Mn(C10H8O6)(H2O)3]n, the two half-MnII atoms lie on inversion centres. One MnII atom is in an octahedral configuration, defined by two O atoms from two monodentate carboxylate groups and four water molecules, and the other MnII atom exists in a different octahedral coordination environment, defined by four O atoms from four monodentate carboxylate groups and two water molecules. The MnII atoms are bridged by a benzene-1,3-dioxyacetate dianion in monodentate and bridging-bidentate modes, forming a two-dimensional layer structure.
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Document Type: Research Article
Publication date: December 1, 2004