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Tetra­aqua­bis(4-carboxy-1H-imidazole-5-carboxyl­ato-2N,O)­calcium(II) monohydrate

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In the title complex, [Ca(H2IDC)2(H2O)4]·H2O, (H2IDC is 4-carboxy-1H-imidazole-5-carboxyl­ate, C5H3N2O4), the CaII atom is located on a twofold rotation axis and is trans-coordinated by two N,O bidentate H2IDC ligands and four water mol­ecules, resulting in a distorted bicapped triangular prismatic configuration. The water molecule is also located on a twofold rotation axis. A three-dimensional network of N—H…O and O—H…O hydrogen bonds help to stabilize the crystal packing.
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Document Type: Research Article

Publication date: December 1, 2004

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