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Bis­(tetra­phenyl­arsonium) tris(2-thio­xo-1,3-di­thiole-4,5-di­thiol­ato)­stannate(IV) acetone solvate at 120 K

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The title compound, (C24H20As)2[Sn(C3S5)3]·C3H6O, is a further example of a salt of the general form Q2[Sn(dmit)3] (dimit is 1,3-di­thiole-2-thione-4,5-di­thiol­ate), where Q, the onium counter-cation, is in this case [AsPh4]+. As in all such compounds, the coordination of the Sn atom is in the form of a distorted octahedron, with Sn—S distances in the range 2.5310 (10)–2.5585 (12) Å provided by three chelating dmit ligands with bite angles in the range 81.59 (3)–87.42 (3)°.
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Document Type: Research Article

Publication date: December 1, 2004

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