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catena-Poly­[[[aqua(1,10-phenanthroline-2N,N′)­copper(II)]--benzene-1,3-dioxy­acetato-2O:O′] dihydrate]

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In the title one-dimensional coordination polymer {systematic name: catena-poly­[[[aqua(1,10-phenanthroline-2N,N′)­copper(II)]--phenyl­enebis­(oxy­acetato)-2O:O′] dihydrate]}, {[Cu(C10H8O6)(C12H8N2)(H2O)]·2H2O}n, the CuII atom has a distorted square-pyramidal coordination geometry, defined by two carboxyl O-atom donors from two benzene-1,3-dioxy­acetate groups, two N-atom donors from the 1,10-phenanthroline ligand and one water mol­ecule. The CuII ions are bridged by benzene-1,3-dioxy­acetate dianions (1,3-BDOA2−), resulting in a one-dimensional chain structure. The intrachain Cu…Cu separation is 9.769 (4) Å. The chains are linked into a three-dimensional supramolecular network via hydrogen bonds and – stacking interactions.
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Document Type: Research Article

Publication date: December 1, 2004

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