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catena-Poly­[[aqua­nitritosilver(I)]--1,4-di­aza­bi­cyclo­[2,2,2]­octane-2N:N′]

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The title compound, [Ag(NO2)(C6H12N2)(H2O)]n, is a polymeric 1,4-di­aza­bi­cyclo­[2,2,2]­octane–AgI complex. Each Ag atom is five-coordinated by two N atoms from two different 1,4-di­aza­bi­cyclo­[2,2,2]­octane ligands, two O atoms of one nitrite anion and another O atom of a coordinated water mol­ecule, forming a severely distorted square-pyramidal coordination environment. In the crystal structure, mol­ecules are connected by intermolecular O—H…O hydrogen bonds, forming a three-dimensional network.
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Document Type: Research Article

Publication date: December 1, 2004

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