The title compound, [Ag(NO2)(C6H12N2)(H2O)]n, is a polymeric 1,4-diazabicyclo[2,2,2]octane–AgI complex. Each Ag atom is five-coordinated by two N atoms from two different 1,4-diazabicyclo[2,2,2]octane ligands, two O atoms of one nitrite anion and another O atom of a coordinated water molecule, forming a severely distorted square-pyramidal coordination environment. In the crystal structure, molecules are connected by intermolecular O—H…O hydrogen bonds, forming a three-dimensional network.
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Document Type: Research Article
Publication date: December 1, 2004