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The heterometallic cadmium–silver complex cis‐bis[dicyanidoargentato(I)‐κN]bis(5,5′‐dimethyl‐2,2′‐bipyridyl‐κ2N,N′)cadmium(II) monohydrate

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In the title complex, [Ag2Cd(CN)4(C12H12N2)2]·H2O or cis‐[Cd{Ag(CN)2}2(5,5′‐dmbpy)2]·H2O, where 5,5′‐dmbpy is 5,5′‐dimethyl‐2,2′‐bipyridyl, the asymmetric unit consists of a discrete neutral [Cd{Ag(CN)2}2(5,5′‐dmbpy)2] unit and a solvent water molecule. The CdII cation is coordinated by two bidentate chelate 5,5′‐dmbpy ligands and two monodentate [AgI(CN)2] anions, which are in a cis arrangement around the CdII cation, leading to an octahedral CdN6 geometry. The overall structure is stabilized by a combination of intermolecular hydrogen bonding, and AgI...AgI and π–π interactions, forming a three‐dimensional supramolecular network.
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Document Type: Research Article

Publication date: October 15, 2013

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