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Poly[diaqua[μ4‐4‐(isonicotinamido)phthalato]nickel(II)] displaying an sra topology

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In the title compound, [Ni(C14H8N2O5)(H2O)2] n , the NiII cation is six‐coordinate with a slightly distorted octahedral coordination geometry and the 4‐(isonicotinamido)phthalate ligand links the NiII centres into a three‐dimensional structure with sra topology. The structure is also stabilized by N—H...O hydrogen bonding between the uncoordinated amide groups of the ligand and extensive O—H...O hydrogen bonding between the two coordinated water molecules. The magnetic and thermal stability properties of the title compound are also discussed.
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Document Type: Research Article

Affiliations: Key Laboratory of Functional Organometallic Materials, Hengyang Normal University, Department of Chemistry and Materials Science, Hengyang, Hunan 421008, People's Republic of China

Publication date: October 15, 2013

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