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The supramolecular structure of a cadmium complex with the new functionalized terpyridine ligand 4′‐[4‐(pyrimidin‐5‐yl)phenyl]‐2,2′:6′,2′′‐terpyridine (L1): aqua(L1‐κ3N,N′,N′′)(nitrato‐κ2O,O′)(nitrato‐κO)cadmium(II) dihydrate

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The monomeric title compound, aqua(nitrato‐κ2 O,O′)(nitrato‐κO){4′‐[4‐(pyrimidin‐5‐yl)phenyl]‐2,2′:6′,2′′‐terpyridine‐κ3 N,N′,N′′}cadmium(II) dihydrate, [Cd(NO3)2(C25H17N5)(H2O)]·2H2O, consists of a seven‐coordinated CdII centre bound to the novel 4′‐[4‐(pyrimidin‐5‐yl)phenyl]‐2,2′:6′,2′′‐terpyridine (L1) ligand (behaving as a tridentate chelate), two nitrate anions (as chelating–bidentate and monodentate ligands) and a water O atom. Both chelating groups define the base of a slightly deformed pentagonal bipyramid, while the monocoordinated ligands occupy the apices. The four heterocycles in L1 form a planar skeleton, while the central benzene ring is rotated from this planar geometry by more than 30°, probably because of packing effects. Noncovalent interactions lead to the formation of columnar arrays parallel to [100].
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Document Type: Research Article

Publication date: August 15, 2013

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