Skip to main content
padlock icon - secure page this page is secure

Tribenzylphosphane and its hydrochloride salt, tribenzylphosphonium hydrogen dichloride–tribenzylphosphane (1/1)

Buy Article:

$52.00 + tax (Refund Policy)

Tribenzylphosphane, PBz3 (C21H21P), crystallizes in a notably different unit cell to its Group 15 analogues NBz3 and SbBz3. The packing is dominated by face–edge π‐interactions which result in infinite columns of molecules parallel to the b axis; these columns are linked by further face–edge π‐interactions into sheets of columns parallel to the [101] direction. Its hydrochloride salt, tribenzylphosphonium hydrogen dichloride–tribenzylphosphane (1/1), lies on a threefold axis within a trigonal crystal system. It exists in the solid state as a hydrogen‐bridged dimer with the composition [H(PBz3)2]+[HCl2] (C42H43P2 +¬∑HCl2 ). The cation is the first structurally authenticated example of a phosphane acting as a hydrogen‐bond acceptor to a phosphonium group and the cations are linked into a three‐dimensional network through intermolecular face–edge π‐interactions.
No References
No Citations
No Supplementary Data
No Article Media
No Metrics

Document Type: Research Article

Affiliations: Chemistry, University of Southampton, Highfield, Southampton SO17 1BJ, England

Publication date: May 15, 2013

  • Access Key
  • Free content
  • Partial Free content
  • New content
  • Open access content
  • Partial Open access content
  • Subscribed content
  • Partial Subscribed content
  • Free trial content
Cookie Policy
X
Cookie Policy
Ingenta Connect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more