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A one‐dimensional ABX3‐type coordination polymer: catena‐poly[benzyltrimethylammonium [tri‐μ‐chlorido‐cadmium(II)]]

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The crystal structure of the title novel one‐dimensional ABX 3‐type organic–inorganic hybrid complex {(C10H16N)[CdCl3]} n , (I), consists of benzyltrimethylammonium (Me3BzN+) cations and one‐dimensional anionic {[Cd(μ‐Cl)3]} chains. Each CdII centre is hexacoordinated by bridging chloride ligands, giving a slightly distorted octahedral Cd(μ‐Cl)6 arrangement. The octahedra are linked by two opposite shared faces, giving rise to an almost perfectly linear anionic {[Cd(μ‐Cl)3]} chain in the a‐axis direction. Me3BzN+ cations located in the inter‐chain spaces balance the charge. Noncovalent static attracting forces (Coulombic and van der Waals forces) and nonclassical C—H...Cl hydrogen‐bond interactions stabilize the crystal structure.
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Document Type: Research Article

Affiliations: College of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096, People's Republic of China

Publication date: May 15, 2013

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