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A fourfold interpenetrating diamondoid three‐dimensional coordination polymer: poly[[[μ2‐1,2‐bis(pyridin‐4‐yl)ethene‐κ2N:N′](μ2‐5‐hydroxyisophthalato‐κ2O1:O3)zinc(II)] 1,2‐bis(pyridin‐4‐yl)ethene hemisolvate]

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In the title compound, {[Zn(C8H4O5)(C12H10N2)]·0.5C12H10N2} n or {[Zn(HO‐BDC)(bpe)]·0.5bpe} n [HO‐H2BDC is 5‐hydroxyisophthalic acid and bpe is 1,2‐bis(pyridin‐4‐yl)ethene], the asymmetric unit contains a ZnII atom, one HO‐BDC ligand, one coordinated bpe ligand and half a noncoordinating bpe molecule with crystallographic inversion symmetry. Each ZnII centre is four‐coordinated by two O atoms from two distinct HO‐BDC ligands and two N atoms from two different bpe ligands in a ZnO2N2 coordination environment. The three‐dimensional topology of the title compound corresponds to a fourfold interpenetrating diamondoid coordination polymer network, with the uncoordinated bpe ligands located in the cavities, hydrogen bonded to the main network via the hydroxy group of the HO‐H2BDC ligand.
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Document Type: Research Article

Affiliations: Guangdong Provincial Public Laboratory of Analysis and Testing, Technology Guangdong Institute of Analysis, Guangzhou 510070, People's Republic of China

Publication date: April 15, 2013

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