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trans‐Chloridobis[(Z)‐1‐imino‐1‐methoxyethane‐κN](triphenylphosphane‐κP)platinum(II) chloride monohydrate

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The title compound, [PtCl(C3H7NO)2(C18H15P)]Cl·H2O or trans‐[PtCl{Z‐HN=C(Me)OMe}2(PPh3)]Cl·H2O, crystallizes from an acetone solution of isomeric trans‐[PtCl{E‐HN=C(Me)OMe}2(PPh3)]Cl. The two HN=C(Me)OMe ligands show typical π‐bond delocalization over the N—C—O group [Cini, Caputo, Intini & Natile (1995). Inorg. Chem. 34, 1130–1137] and have the unprecedented Z–anti configuration. The relative orientation of the imino ether ligands is head‐to‐tail.
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Document Type: Research Article

Affiliations: Dipartimento di Chimica, Università degli Studi di Bari Aldo Moro, via E. Orabona 4, 70125 Bari, Italy

Publication date: November 15, 2012

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