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1,3‐Ninhydrin dihydrazone featuring an R44(12) motif with symmetry and comprising only N and H atoms

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In the title compound [systematic name: (1Z,3Z)‐1,3‐dihydrazinylidene‐1H‐inden‐2(3H)‐one], C9H8N4O, isolated molecules possess approximate noncrystallographic C 2v symmetry and their cis conformation and planarity are assisted by a pair of short intramolecular N—H...O hydrogen bonds. Each molecule is asymmetrically involved in an extensive three‐dimensional network of N—H...O and N—H...N hydrogen bonds, and the structure also exhibits weaker π–π and C=O...C interactions. The structure features an R 4 4(12) motif consisting solely of N and H atoms and possessing crystallographic symmetry.
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Document Type: Research Article

Publication date: September 15, 2012

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