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Poly[(μ3‐benzene‐1,4‐dicarboxylato)di‐μ‐chlorido‐(triethanolamine)dicadmium(II)]: a cadmium–halide coordination polymer with a hydrogen‐bonded three‐dimensional framework

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The structure of the title compound, [Cd2(C8H4O4)Cl2(C6H15NO3)] n , consists of one‐dimensional chains in which each centrosymmetric tetranuclear Cd4Cl4O2 cluster is terminated by two chelating triethanolamine (teaH3) ligands but linked to two adjacent clusters through four bridging benzene‐1,4‐dicarboxylate (bdc) ligands. The tetranuclear Cd4Cl4O2 clusters are held together via bridging Cl and O atoms. Three directional hydrogen bonds from the multi‐podal hydroxy groups of the teaH3 ligand stabilize and extend the one‐dimensional chains into a three‐dimensional framework. All three hydroxy groups of the teaH3 ligand form hydrogen bonds, illustrating the fact that the teaH3 ligand can serve as an excellent hydrogen‐bond donor.
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Document Type: Research Article

Affiliations: Key Laboratory of Jiangxi University for Functional Materials Chemistry, School of Chemistry and Chemical Engineering, Gannan Normal University, Ganzhou, Jiangxi 341000, People's Republic of China

Publication date: April 15, 2012

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