Skip to main content
padlock icon - secure page this page is secure

‐Poly[[silver(I)‐μ‐1,3‐bis(4‐pyridyl)propane] hemi(naphthalene‐1,5‐disulfonate) dihydrate]: a three‐dimensional metallo‐supramolecular sandwich lamellar network

Buy Article:

$52.00 + tax (Refund Policy)

The title compound, {[Ag(C13H14N2)](C10H6O6S2)0.5·2H2O} n , (I), features a three‐dimensional supramolecular sandwich architecture that consists of two‐dimensional cationic layers composed of polymeric chains of silver(I) ions and 1,3‐bis(4‐pyridyl)propane (bpp) ligands, linked by Ag...Ag and π–π interactions, alternating with anionic layers in which uncoordinated naphthalene‐1,5‐disulfonate (nds2−) anions and solvent water molecules form a hydrogen‐bonded network. The asymmetric unit consists of one AgI cation linearly coordinated by N atoms from two bpp ligands, one bpp ligand, one half of an nds2− anion lying on a centre of inversion and two solvent water molecules. The two‐dimensional {[Ag(bpp)]+} n cationic and {[(nds)·2H2O]2−} n anionic layers are assembled into a three‐dimensional supramolecular framework through long secondary coordination Ag...O interactions between the sulfonate O atoms and AgI centres and through nonclassical C—H...O hydrogen bonds.
No References
No Citations
No Supplementary Data
No Article Media
No Metrics

Document Type: Research Article

Affiliations: Institute of Materials Physical Chemistry, Huaqiao University, Xiamen, Fujian 361021, People's Republic of China

Publication date: September 15, 2011

  • Access Key
  • Free content
  • Partial Free content
  • New content
  • Open access content
  • Partial Open access content
  • Subscribed content
  • Partial Subscribed content
  • Free trial content
Cookie Policy
X
Cookie Policy
Ingenta Connect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more