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Reactions of (Et4N)[Tp*WS3] [Tp* is hydridotris(3,5‐dimethylpyrazol‐1‐yl)borate] with CuSCN in MeCN in the presence of melamine afforded the title neutral dimeric cluster [Cu4W2(C15H22BN6)2(NCS)2S6(C2H3N)2] or [Tp*W(μ2‐S)23‐S)Cu(μ2‐SCN)(CuMeCN)]2, which has two butterfly‐shaped [Tp*WS3Cu2] cores bridged across a centre of inversion by two (CuSCN) anions. The S atoms of the bridging thiocyanate ligands interact with the H atoms of the methyl groups of the Tp* units of a neighbouring dimer to form a C—H...S hydrogen‐bonded chain. The N atoms of the thiocyanate anions interact with the H atoms of the methyl groups of the Tp* units of neighbouring chains, affording a two‐dimensional hydrogen‐bonded network.
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Document Type: Research Article

Affiliations: Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, People's Republic of China

Publication date: July 15, 2011

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