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The title compound, [Ti2Cl6(C2H6N)2(C2H7N)2], is a binuclear octahedral complex lying about an inversion centre. There are four different chloride environments, two terminal [Ti—Cl = 2.2847 (5) and 2.3371 (5) Å] and two bridging [Ti—Cl = 2.4414 (5) and 2.6759 (5) Å], with the Ti—Cl distances being strongly influenced by both the ligand trans to the chloride and whether or not the chloride anion is bridging between the two TiIV centres. The compound forms a two‐dimensional network in the solid state, with weak intermolecular C—H...Cl interactions giving rise to a planar network in the (10) plane.
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Document Type: Research Article

Affiliations: Department of Chemistry, University College London, 20 Gordon Street, London WC1H 0AJ, England

Publication date: July 15, 2011

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