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A new rhombohedral modification of EuNi

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A rhombohedral modification of europium pentanickel indide, r‐EuNi5In, crystallizes in the Rm space group and adopts the UCu5In structure type. The structure is closely related to the hexagonal, h‐EuNi5In, form (CeNi5Sn type). Both EuNi5In modifications are composed of CaCu5 (EuNi5)‐, MgCu2 (InNi2)‐ and NiAs (EuNi)‐type slabs in a 1:2:1 ratio. The atoms in the structure have high coordination numbers, viz. 20 and 18 for europium, 14 for indium, and 12 and 10 for nickel. The structure features a two‐dimensional network of 2 [Ni8] tetrahedral clusters arranged in the ab plane.
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Document Type: Research Article

Publication date: July 15, 2011

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