Skip to main content
padlock icon - secure page this page is secure

Palladium(II)‐N‐heterocyclic carbene complexes: synthesis, characterization and catalytic application

Buy Article:

$52.00 + tax (Refund Policy)

N‐Heterocyclic carbenes (NHCs) are of great importance and are powerful ligands for transition metals. A new series of sterically hindered benzimidazole‐based NHC ligands (LHX) (2a, 2b, 2c, 2d, 2e, 2f), silver–NHC complexes (3a, 3b, 3c, 3d, 3e, 3f) and palladium–NHC complexes (4a, 4b, 4c, 4d, 4e, 4f) have been synthesized and characterized using appropriate spectroscopic techniques. Studies have focused on the development of a more efficient catalytic system for the Suzuki coupling reaction of aryl chlorides. Catalytic performance of Pd–NHC complexes and in situ prepared Pd(OAc)2/LHX catalysts has been investigated for the Suzuki cross‐coupling reaction under mild reaction conditions in aqueous N,N‐dimethylformamide (DMF). These complexes smoothly catalyzed the Suzuki–Miyaura reactions of electron‐rich and electron‐poor aryl chlorides. Copyright © 2014 John Wiley & Sons, Ltd. These catalysts showed smoothly catalytic performance towards the Suzuki‐Miyaura reactions of the electron‐reach and electron‐poor aryl chlorides.
No References
No Citations
No Supplementary Data
No Article Media
No Metrics

Keywords: N‐heterocyclic carbene; Suzuki reaction; palladium–NHC; phenyl boronic acid

Document Type: Research Article

Publication date: June 1, 2014

  • Access Key
  • Free content
  • Partial Free content
  • New content
  • Open access content
  • Partial Open access content
  • Subscribed content
  • Partial Subscribed content
  • Free trial content
Cookie Policy
X
Cookie Policy
Ingenta Connect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more