Skip to main content
padlock icon - secure page this page is secure

Reactions of Early Transition Metal - Carbon Bonds with N-Heterocycles

Buy Article:

Your trusted access to this article has expired.

$63.00 + tax (Refund Policy)

Heterocycles are ubiquitous in biological compounds and methods to functionalize them have been of long standing interest. Reactions of early transition metal-carbon bonds with heterocycles are important in two major areas: (1) activation and functionalization of heterocycles and (2) ring-opening of aromatic heterocycles. In the first area, metalcarbon  bonds determine ortho-metalation and insertion of unsaturated substrates to yield functionalized heterocycles. In the latter area, metal-element multiple bonds become important and provide the driving force for ring-opening reactions. This review will focus on reactions of nitrogen-containing heterocycles. Early transition metals are defined as elements belonging to groups III-V, the lanthanides, and the actinides; the reactivity of complexes featuring the metal in its highest oxidation state (d0fn electron count) and a carbon-based ligand will be described.





No References
No Citations
No Supplementary Data
No Article Media
No Metrics

Keywords: Complexes; N-Heterocycles; Transition Metal; lanthanides; ligand; ortho-metalation; oxidation state

Document Type: Research Article

Publication date: 01 November 2008

  • Access Key
  • Free content
  • Partial Free content
  • New content
  • Open access content
  • Partial Open access content
  • Subscribed content
  • Partial Subscribed content
  • Free trial content
Cookie Policy
X
Cookie Policy
Ingenta Connect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more