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Non-Conventional Redox Chemistry of Dihydropyridines and Pyridinium Salts

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The classical redox chemistry of the NADH-NAD+ cofactors and their synthetic analogues (dihydropyridines and pyridinium salts) has been extended to non-biomimetic processes. These involve reactions that bypass the electron transfer processes and allow the functionalization of the heterocyclic parent systems with a broad variety of carbon- and heteroatom-based functional groups. The scope of the methodology, and its applications to organic synthesis are analyzed.
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Keywords: dihydropyridines; non-biomimetic; pyridinium salts; redox chemistry

Document Type: Review Article

Affiliations: Laboratory of Organic Chemistry, Faculty of Pharmacy, University of Barcelona, Av. Joan XXIII sn, 08028 Barcelona, Spain

Publication date: May 1, 2004

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