@article {Banerjee:2010:1573-4137:432, title = "Low Temperature Synthesis of Nano-Crystalline CaCu3Ti4O12 Through a Fuel Mediated Auto-Combustion Pathway", journal = "Current Nanoscience", parent_itemid = "infobike://ben/cnano", publishercode ="ben", year = "2010", volume = "6", number = "4", publication date ="2010-08-01T00:00:00", pages = "432-438", itemtype = "ARTICLE", issn = "1573-4137", url = "https://www.ingentaconnect.com/content/ben/cnano/2010/00000006/00000004/art00016", doi = "doi:10.2174/157341310791658955", keyword = "Dielectric material, nano-crystalline perovskites, solution combustion", author = "Banerjee, Nirupam and Krupanidhi, S. B.", abstract = "A novel, cost effective, environment-friendly and energetically beneficial alternative method for the synthesis of giant dielectric pseudo-perovskite material CaCu3Ti4O12 (CCTO) is presented. The method involved auto-combustion of an aqueous precursor solution in oxygen atmosphere with the help of external fuels and is capable of producing high amount of CCTO at ultra-low temperature, in the combustion residue itself. The amount of phase generated was observed to be highly dependent on the combustion process i.e. on the nature and amount of external-fuels added for combustion. Two successful fuel combinations capable of producing reasonably higher amount of the desired compound were investigated. On a structural characterization grain size was observed to decrease drastically to nano-dimension compared to submicron-size that was obtained in a traditional sol-gel combustion and subsequent cacination method. Therefore, the method reported can produce nano-crystalline CaCu3Ti4O12 ceramic matrix at an ultra-low temperature and is expected to be applicable for other multifunctional perovskite oxide materials. ", }