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Unusual Red-Shift and Enhanced Photoluminescence of BaMgAl10O17:Eu2+ Phosphor Under Ultraviolet A Excitation for Modern Lighting Systems

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An unconventional red-shift but enhanced photoluminescence (PL) under ultraviolet A (UV-A) irradiation of Eu2+ doped Barium Magnesium Aluminate (BAM) phosphor prepared in both bulk and nanoforms useful for modern lighting applications has been presented. The solid-state reaction and solution combustion approaches were used for the preparation of phosphors with post-annealing step in reduced atmosphere. A significant broad blue-green (˜500 nm) PL associated with the transition of Eu2+ from 4f 6 5d1 excited state to the 4f 7 ground state has been observed. The observed shifts and PL intensities were found to be extremely reliant on the thermal processing parameters during the synthesis of phosphor/nanophosphormaterials. It’s also important to note that the size of the phosphor particles have significant role in defining the red-shift of PL due to quantum confinement effect. Detailed structural and morphological characterizations were also done in this paper. The results are promising and suggest that the BAM phosphor is highly desirable for enhancing the brightness levels in modern lighting and display systems.
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Keywords: Nanophosphor; Photoluminescence; Quantum Confinement; Solution-Combustion

Document Type: Research Article

Affiliations: 1: Department of Physics, Kakatiya University, Warangal 506009, Telangana, India 2: Luminescent Materials and Devices Group, Department of Physics, National Institute of Technology, Warangal 506004, Telangana, India 3: Nanophotonics Laboratory, Department of Physics, Indian Institute of Technology-Delhi, Hauz Khas, New Delhi 110016, India

Publication date: June 1, 2020

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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