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Catalytic Performance of Supported Pd Catalyst Prepared with Different Palladium Precursors for Catalytic Combustion of BTH

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Catalytic combustion of benzene, toluene, and hexane (BTH) was carried out to investigate in this study the effect of palladium precursor on the property and performance of 1 wt.% Pd/γ-Al2O3. Properties were characterized by X-ray diffraction (XRD), Brunauer Emmett Teller (BET) surface area, temperature programmed reduction (TPR), Transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS) analyses. When palladium precursor was used to prepare the catalyst, it had a great effect on the property and performance of the supported palladium catalyst. Total acidity, size of palladium particle, and oxidation state of palladium were associated with catalytic activity of the catalyst. Higher total acidity of the catalyst and larger particle size of palladium favorably affected the catalytic activity. In addition, palladium species with high oxidation state might be useful to increase catalytic activity in BTH combustion.
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Keywords: Catalytic Oxidation; Palladium; Particle Size; Toluene

Document Type: Research Article

Affiliations: 1: Department of Environmental Engineering, Sunchon National University, Suncheon, 57975, Korea 2: School of Environmental Engineering, University of Seoul, Seoul 02504, Korea 3: Department of Physics, Mokpo National University 61, Muan 58554, Korea 4: Department of Fire Service Administration, Honam University, Gwangju 62399, Korea 5: Department of Environment and Energy Engineering, Chonnam National University, Gwangju 61186, Korea 6: Department of Polymer Engineering, Sunchon National University, Suncheon, 57975, Korea 7: Department of Environmental Education, Mokpo National University 61, Muan 58554, Korea

Publication date: February 1, 2019

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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