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Hydroxyapatite (HA) Modified Nanocoating Enhancement on AZ31 Mg Alloy by Combined Surface Mechanical Attrition Treatment and Electrochemical Deposition Approach

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Hydroxyapatite (HA) nanocoating was electrodeposited on the surface mechanical attrition treated (SMATed) AZ31 magnesium alloy. Phases, morphologies and the adhesion of coating were characterized by X-ray diffraction, scanning electron microscopy (SEM) and 3D optical profiler. The corrosion resistance of the HA coating was tested by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). The results showed that the HA coating on SMATed sample had a better crystallization than that on original one. The thickness of HA coating increased from 25 to 40 μm. The bonding strength between HA coating and SMATed substrate was higher than that between the coating and untreated counterpart. Potentiodynamic polarization and EIS demonstrated that the corrosion current density of HA coating on SMATed substrate decreased by 30.84% than that on original. The corrosion potential shifted 80.3 mV to the positive direction. The corrosion resistance of coatings on SMATed sample was significantly enhanced. The immersion experiments showed that the HA coatings on SMATed sample exhibited a better biological activity.
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Keywords: AZ31 Mg Alloy; Coatings; Electrodeposition; Hydroxyapatite; Surface Mechanical Attrition Treatment

Document Type: Research Article

Affiliations: 1: College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan, Shanxi 030024, China 2: College of Basic Medical, Shanxi Medical University, Taiyuan, Shanxi 030001, China 3: Integrated Composites Laboratory (ICL), Department of Chemical and Biomolecular Engineering, University of Tennessee, Knoxville, TN 37996, USA 4: State Key Laboratory of Marine Resource Utilization in South China Sea, Hainan University, Haikou 570228, P. R. China 5: Department of Chemistry, Faculty of Science and Arts and Promising Centre for Sensors and Electronic Devices (PCSED), Najran University, Najran 11001, Kingdom of Saudi Arabia

Publication date: 01 February 2019

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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