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Preparation of Octadecylamine-Graphene/MgCl2-Supported Ziegler-Natta Catalyst and Its Application in Ethylene Polymerization

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A facile coagglomeration method for preparing a long alkyl chain modified graphene oxide (MGO)/MgCl2-supported Ti-based Ziegler-Natta catalyst was reported. The effects of MGO on the catalyst morphology and activity for ethylene polymerization were examined. The resultant polyethylene (PE)/MGO nanocomposites exhibited a layered morphology, with the MGO fillers being well dispersed and exhibiting strong interfacial adhesion to the PE matrix. The thermal stability and mechanical properties of the PE were significantly enhanced with the introduction of a small amount of the MGO filler. Thus, this work provides a facile approach to the production of high-performance PE.
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Keywords: Graphene; In-Situ Polymerization; Nanocomposite; Polyethylene; Ziegler-Natta

Document Type: Research Article

Affiliations: 1: College of Food Science and Engineering, National Engineering Lab. for Wheat and Corn Deep Processing, Jilin Agricultural University, Changchun, 130118, China 2: Department of Polymer Science and Engineering, Kyungpook National University, Daegu, 41566, Korea 3: CAS Key Lab. of Synthetic Rubber, Changchun Institute of Applied Chemistry, Chinese Academy of Science, Changchun, 130022, China

Publication date: April 1, 2018

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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