Hybrid Lead Halide Layered Perovskites with Silsesquioxane Interlayers
Hybrid organic—lead halide perovskites exhibit remarkable properties as semiconductors and light absorbers. Here, we report the formation of silsesquioxane—lead halide hybrid layered perovskites. We prepared silsesquioxane with a cubic cage-like structure and fabricated hybrid silsesquioxane—lead halide layered perovskites in a self-assembled manner. It is demonstrated that the silsesquioxane maintain their cage-like structure between lead halide perovskite layers. The silsesquioxane—lead halide perovskites also show excitonic absorption and emission in the visible light region similar to typical lead halide layered perovskites.
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Document Type: Research Article
Affiliations: National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan
Publication date: 01 January 2018
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