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Highly Fluorinated Polymer-Inorganic Nanoparticle Composites Processable with Fluorous Solvents

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In this article, we report the concept of solution-processable, composite materials derived from fluorinated high-k metal oxide nanoparticles and a highly fluorinated polymer binder. Hydroxylated BaTiO3 surface was modified successfully by ligand substitution reactions using a block copolymer composed of semi-perfluorodecyl methacrylate (FDMA) and tert-butyl methacrylate (tBMA). The resulting BaTiO3 particles dispersed well in HFE-7500 and their solution with a random copolymer binder, P(FDMA-r-tBMA), could form decent insulator layers. A metal-insulator-metal diode fabricated with the spin-coated BaTiO3 and fluorinated polymer binder showed that the dielectric constant of the composite films was ca. 20 at 106 Hz. This result suggests that the polymeric fluorous ligand-modified nanoparticles could be useful components for printed electronics applications fabricated with delicate organic electronic materials.
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Keywords: Dielectric Materials; Fluorinated Polymer-Inorganic Hybrid; Fluorous Solvents; RAFT Polymerization; Spin-Coating Process

Document Type: Research Article

Affiliations: 1: Department of Polymer Science and Engineering, Inha University, Incheon 22212, Republic of Korea 2: Display Materials and Components Research Center, Korea Electronics Technology Institute, Seongnam-si, Gyeonggi-do 13509, Republic of Korea

Publication date: August 1, 2017

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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