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Fibrous MnO2 Nanoparticles with (2 × 2) Tunnel Structures. Catalytic Activity in the Total Oxidation of Volatile Organic Compounds

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Manganese oxides having 2 × 2 tunnel structures (cryptomelanes) have been synthesized by a milling method in order to test their efficiency as catalysts for the abatement of volatile organic compounds, using toluene as probe molecule. These materials present excellent textural properties, arising from the nanofiber morphology and were active for toluene total oxidation. DRIFTS of the adsorbed phase allow proposing the role of lattice oxygen in the catalytic reaction.
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Keywords: CATALYTIC OXIDATION; CRYPTOMELANE; NANOFIBERS; REDOX PROPERTIES; VOC'S

Document Type: Research Article

Publication date: June 1, 2009

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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