Polyol Preparation by Liquefaction of Technical Lignins in Crude Glycerol
This work reports a study of polyol synthesis through liquefaction of technical lignins in crude glycerol by means of 1H and 31P NMR spectroscopy. The polyols are intended for preparation of polyurethane foam; thus, it is important to know how different lignin
types as well as crude glycerol influence and contribute to the final polyol hydroxyl contents. Polyols prepared from organosolv lignin, kraft lignin and lignosulphonate had hydroxyl numbers suitable for rigid foam of 435, 515 and 529 mgKOH/g, respectively. The polyols differed in composition
with glycerol, showing significant variation. During liquefaction the glycerol content was mostly reduced through bonding with lignin, and to a lesser extent monoacylglycerol and diacylglycerol formation through transesterification with fatty acid ethyl esters. It is concluded that crude glycerol
can potentially replace petroleum-derived polyols as liquefaction solvent and that different types of technical lignin have a strong impact on the resulting bio-based polyol hydroxyl contents.
Keywords: 31P NMR; BIODIESEL BY-PRODUCT; LIGNIN; POLYURETHANE; PULP AND PAPER BY-PRODUCT; RENEWABLE POLYOLS
Document Type: Research Article
Publication date: 01 January 2017
- This journal publishes high quality peer reviewed original research and review articles on macromolecules and additives obtained from renewable/biobased resources. Utilizing a multidisciplinary approach, JRM introduces cutting-edge research on biobased monomers, polymers, additives (both organic and inorganic), their blends and composites. JRM showcases both fundamental aspects and applications of renewable materials. The fundamental topics include the synthesis and polymerization of biobased monomers and macromonomers, the chemical modification of natural polymers, as well as the characterization, structure-property relationships, processing, recycling, bio and environmental degradation and life cycle analysis of the ensuing materials, in view of their potential applications. Within this sustainability approach, green chemistry processes and studies falling within biorefinery contexts are strongly favored.
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