Synthesis and Stability of 1-Phenylethenyl Phosphate Derivatives and their Phosphoryl Transfer Activity
1-Phenylethenyl phosphate derivatives of the monoester type were synthesized via the Perkow reaction. Among them, 2-(2,4-difluorophenyl)ethenyl phosphate was found to be obtained as a pure salt. It turned out that this compound and 2-phenylethenyl phosphate can transfer their phosphoryl groups to AMP in pyridine at elevated temperatures to give ADP.
Keywords: enol phosphate; perkow reaction; phosphoryl transfer; phosphorylation
Document Type: Review Article
Affiliations: CREST, JST (Japan Science and Technology Agency) Nagatsuta, Midori-ku, Yokohama 226-8501, Japan.
Publication date: 01 April 2004
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