Biosynthesis of Silicon–Germanium Oxide Nanocomposites by the Marine Diatom Nitzschia frustulum
The biomineralization capacity of the photosynthetic marine diatom Nitzschia frustulum was harnessed to fabricate Si–Ge oxide nanocomposite materials. Germanium was incorporated into the diatom cell by a two-stage cultivation process. In stage 1, the N. frustulum cell suspension was grown up to cell density of 3 × 106 cells/mL in 0.35 mM silicic acid within a bubble-column photo- bioreactor. In stage 2, when all of the soluble silicon was consumed,0.10 mM Ge(OH)4 or a mixture of 0.020 mM Ge(OH)4 and 0.25 mM Si(OH)4 were added to Si-starved cells. The cells assimi- lated soluble germanium by a surge uptake mechanism. The cell mass was thermally annealed in air at 800°C for 6 h to oxidize carbonaceous materials. The thermally annealed cell biomass was characterized by TEM-EDS, FT-IR, and XRD. These measurements confirmed the formation nanostructured Ge–Si oxides composed of CaSiO3 and Ca3 GeO5.
Keywords: DIATOM; GERMANIUM; NANOSTRUCTURE
Document Type: Review Article
Publication date: 01 January 2005
- Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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