Arsenic Distribution and Adsorption Behavior in the Sediments of the Daliao River System in China
This study investigated the arsenic (As) distribution and adsorption behavior in sediments of the Daliao River System (DRS). Results indicated that the total As was 2.6‐83.1 mg kg−1 in the sediments of the DRS. The pseudo-first order model and intra-particle diffusion model give a good fit of the experimental kinetics data for As, indicating that particle diffusion mechanism may not be the rate controlling step while this mechanism is involved. By comparing the zero equilibrium As concentration (EAsCo) with the actual As concentration in the overlying water of the DRS, all the sediments showed a trend of releasing As. Arsenic exhibited strong adsorption on sediment at pH 4.5‐7. Arsenic retention by sediment was much enhanced by Ca2+ compared to Na+. More As was desorbed by phosphate at low and high pH extremes. The added or sorbed As was mainly transferred to the specifically sorbed fraction and amorphous Fe (Al) oxyhydroxides bound fraction, indicating Fe oxides are a major sorbent of As in sediment.
Document Type: Research Article
Publication date: August 1, 2013
More about this publication?
- Water Environment Research® (WER®) publishes peer-reviewed research papers, research notes, state-of-the-art and critical reviews on original, fundamental and applied research in all scientific and technical areas related to water quality, pollution control, and management. An annual Literature Review provides a review of published books and articles on water quality topics from the previous year. Published as: Sewage Works Journal, 1928 - 1949; Sewage and Industrial Wastes, 1950 - 1959; Journal Water Pollution Control Federation, 1959 - Oct 1989; Research Journal Water Pollution Control Federation, Nov 1989 - 1991; Water Environment Research, 1992 - present.
- Editorial Board
- Information for Authors
- Submit a Paper
- Subscribe to this Title
- Membership Information
- Information for Advertisers
- WEF Bookstore
- ingentaconnect is not responsible for the content or availability of external websites