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High-value Zeolitic Material from Bagasse Fly Ash: Utilization for Dye Elimination

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Abstract:

Bagasse fly ash (BFA), a sugar industry waste, was used to prepare zeolitic material (ZFA) by means of alkaline hydrothermal treatment. ZFA showed improved morphology as a result of this treatment. . The adsorption of the reactive dyes turquoise blue (TB) and brilliant magenta (BM), on both BFA and ZFA, was investigated in a batch contact system. A series of batch experiments revealed that optimal dye removal occurs at a 200 mg/L to 300 mg/L solute concentration, 60 minutes of agitation time, 5 g/L to 10 g/L adsorbent dose, a pH level of 2 to 4, and a temperature of 298 K. ZFA showed enhanced adsorption capacity as compared to BFA. According to the Langmuir equation, the maximum adsorption capacity was 12.66 mg/g and 45.45 mg/g for turquoise blue and brilliant magenta dyes, respectively, on BFA; and 21.74 mg/g and 100.00 mg/g for turquoise blue and brilliant magenta dyes, respectively, on ZFA. Kinetic studies showed that the correlation coefficients best fit with the pseudo-second-order kinetic model, confirming that the adsorption rate was controlled by a hemisorptions process.

Keywords: adsorption; isotherm; kinetics; reactive dyes; zeolite

Document Type: Research Article

DOI: https://doi.org/10.2175/106143013X13596524515744

Publication date: 2013-06-01

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  • Water Environment Research (WER) is published monthly, including an annual Literature Review. A subscription to WER includes access to the latest content back to 1992, as well as access to fast track articles. An individual subscription is valid for 12 months from month of purchase.

    Water Environment Research (WER) publishes peer-reviewed research papers, research notes, state-of-the-art and critical reviews on original, fundamental and applied research in all scientific and technical areas related to water quality, pollution control, and management. An annual Literature Review provides a review of published books and articles on water quality topics from the previous year.

    Published as: Sewage Works Journal, 1928 - 1949; Sewage and Industrial Wastes, 1950 - 1959; Journal Water Pollution Control Federation, 1959 - Oct 1989; Research Journal Water Pollution Control Federation, Nov 1989 - 1991; Water Environment Research, 1992 - present.
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