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Complete Dechlorination of Endosulfan and Lindane Using Mg0/Pd+4 Bimetallic System

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Abstract:

A Mg0/Pd+4 bimetallic system was evaluated to dechlorinate endosulfan and lindane in the aqueous phase. Studies were conducted with endosulfan and lindane separately, with or without acid in a 1:1 (v/v) water:acetone phase. In the absence of any acid, higher degradation of endosulfan and lindane was observed using Mg0/Pd+4 doses of 10/0.5 and 4/0.1 mg/mL, respectively. Acetone plays an important role in facilitating the dechlorination reaction by increasing the solubilities of pesticides. Dechlorination kinetics for endosulfan and lindane (30 and 50 mg/L [30 and 50 ppm] concentration of each pesticide) were conducted with varying Mg0/Pd+4 doses, and the time-course profiles were well-fitted into exponential curves. The optimum observed rate constants (k obs') for endosulfan and lindane were obtained with Mg0/Pd+4 doses of 5/0.5 and 4/0.1 mg/mL, respectively. Gas chromatography-mass spectrometry analyses revealed that endosulfan and lindane were dechlorinated completely into their hydrocarbon skeletons—Bicyclo [2,2,1] hepta 2‐5 diene and benzene, respectively.

Keywords: bimetallic; dechlorination; endosulfan; lindane; magnesium; palladium

Document Type: Research Article

DOI: http://dx.doi.org/10.2175/106143011X12928814445096

Publication date: September 1, 2011

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  • Water Environment Research® (WER®) publishes peer-reviewed research papers, research notes, state-of-the-art and critical reviews on original, fundamental and applied research in all scientific and technical areas related to water quality, pollution control, and management. An annual Literature Review provides a review of published books and articles on water quality topics from the previous year.

    Published as: Sewage Works Journal, 1928 - 1949; Sewage and Industrial Wastes, 1950 - 1959; Journal Water Pollution Control Federation, 1959 - Oct 1989; Research Journal Water Pollution Control Federation, Nov 1989 - 1991; Water Environment Research, 1992 - present.
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